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Mechanochemically induced dechlorination of mono-chlorobiphenyl (BP-Cl) on the surfaces of metal oxides was compared with that on metal hydroxides, using the three metals of Mg, Al, and La as examples. The metal oxides, such as γ-alumina (γ-Al 2 O 3 ), magnesium oxide (MgO) and lanthanum oxide (La 2 O 3 ) showed an efficient ability to dechlorinate the BP-Cl; however,...
A hexabromobenzene (HBB, C 6 Br 6 ) powder was subjected to co-grinding with excess CaO powder in air using a planetary ball mill to investigate mechanochemical debromination of the HBB sample. The reaction proceeds smoothly with an increase in both grinding time and molar ratio of CaO addition. The co-grinding enables us to debrominate HBB, forming CaBr 2 , C and CaCO ...
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