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We report that the catalytic behavior and enantioselectivity of three different chiral Mn(III) salen complexes anchored to traditional supports such as MCM-41 (38-Å pore diameter) and delaminated zeolitic materials ITQ-2 and ITQ-6 strongly depend on whether the complexes are attached to the surfaces through the chiral equatorial tetradentate salen ligand or via the apical ligand. As for the case of...
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