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The adsorption and dissociation of trichloroethene (TCE) on PdCu(110) have been investigated under the view of high resolution electron energy loss spectroscopy (HREELS) and first-principle quantum chemical calculations.At 180 K and after an exposure of 10 L, TCE is physisorbed on the surface. The HREELS spectrum is similar to the gas-phase one, measured by infrared spectroscopy. There are small shifts...
Self-consistent calculations based on density functional theory with gradient corrections are used to compare the adsorption of NO on Pd(100) and Pd 3 Mn(100). There are two types of Pd 3 Mn(100) surfaces, one with only Pd atoms (A) and one with Pd and Mn atoms alternately ordered (B). For adsorption on surface A, the adsorption sites are in the same stability order as for palladium,...
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