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In TWIP steels, the addition of Ce and P results in the finer as-cast structure which arises from the pinning effect of the Ce-rich compounds against the coalescence of the neighboring columnar grains. Cerium compounds consists of three groups: a multilayered core-shell structure composed of (Ce,Ca)(S,Se), Ce(S,Se,As,P) and CeP, a structure consisting of Ce(As,P) and CeP, and the CeP compound independently...
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