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This chapter is devoted to phosphinous amides, a particular class of tervalent aminophosphanes. First, attention is focused on their stability and synthetic procedures. Reports dealing with their prototropic equilibrium and main group chemistry are also considered. Last but not least the really important applications of these species as metal ligands in the field of catalysis are reviewed, including...
The molecular structures of two aminophosphonium salts (bromide and tetrafluoroborate) have been determined by X-ray analysis. They have similar conformations and hydrogen bond (HB) networks: the N–H acid proton is bonded to the anion and, in the case of the fluoroborate, to the oxygen atom of the phosphine oxide, forming a pseudo six-membered ring closed by a weak N–H⋅⋅⋅O intramolecular hydrogen...
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