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In our ongoing studies of high valent manganese dimers of the general formula [Mn IV (Schiff base)(μ-O)] 2 as models for the oxygen evolving complex (OEC) of photosystem II (PSII), we now report several new Mn complexes that allow us to define a magneto-structural correlation between the Heisenberg exchange constant, J, from the Heisenberg exchange equation (H=-2J[S 1 ...
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