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We have recently shown that molecular glasses, small molecules capable of readily forming glassy solids as opposed to crystals, can be designed by exploiting molecular association through strong and directional intermolecular interactions, as exemplified by several members of the bis(mexylamino)triazine family. Herein, 43 new bis(mexylamino)triazine derivatives were synthesized, 31 of which have been...
Like other derivatives of hexaphenylbenzene, hexakis(4-nitrophenyl)benzene (1) crystallizes under a variety of conditions as layered structures in which significant quantities of guests are included in spaces between the layers or within them. In structures of nitroarene 1, multiple intermolecular N⋯O interactions of NO 2 groups help to hold the layers together and determine how the molecular...
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