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An acyclic diimine ligand, H 4 L 1 , formed in methanol from the condensation of 1,4-diformyl-2,3-dihydroxybenzene (1) with two equivalents of 2-aminoethanol, was reacted with two equivalents of solid zinc(II) acetate dihydrate. Diffusion of diethyl ether into the reaction solution yielded a mixture of orange crystals of an octanuclear complex, [Zn II8 (H 2 L ...
Syntheses, structures and properties of polymetallic complexes prepared from both acyclic and cyclic ligands derived from the dialdehyde 1,4-diformyl-2,3-dihydroxybenzene (1), and two close analogues which also feature the 1,4-dicarbonyl-2,3-dihydroxy motif, are reviewed.
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