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Carbon rich compounds such as C60 buckminsterfullerene, conjugated oligoynes, and single-walled carbon nanotubes offer advantages as core templates for the design of dendrimers with a predefined shape because of their rigid structures. Ih-symmetrical C60 permits the stereochemically-controlled attachment of anchor groups for the addition of dendrons and allows the realization of the formation...
Through functionalization of carbon nanotubes, i.e., the attachment of appropriate chemical functionalities onto their conjugated sp2 carbon scaffold, the prerequisites for faciliating the production of possible applications of such nanostructures are established. The derivatized tubes exhibit improved properties with respect to solubility and ease of dispersion, manipulation and processibility,...
The fullerenes have been established as new and versatile building blocks in organic chemistry. A large number of fascinating fullerene derivatives, especially of the icosahedral buck-minsterfullerene C60, have been synthesized. The chemistry of C60 continues to be good for many surprises. However, based on present knowledge a series of reactivity principles can be deduced which makes derivatization...
The aesthetically pleasing molecular architectures of fullerenes and nanotubes are appealing not only because of their beauty but also because they are responsible for the many unprecedented chemical and physical properties of this compound class. Although succession of exciting new discoveries continues unabated fullerene research has become a mature science. It is now possible to predict fullerene...
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