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Chemically modified electrodes based on complexes of transition metals with N,N′-ethylenebis(salicylimine) (salen) type ligands are reported to act as redox mediators due to axial coordination of exogeneous ligands to metal atom in oxidized form of complex. Thus such electrodes can be used as amperometric and voltammetric detectors of various compounds. However, effects of ligand structure and ligand-analyte...
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