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The conjugation of the gold(I) complex having planar phenyl isocyanide or bulky triphenylphosphine with 6-ethynyl-1-octyluracil afforded the corresponding gold(I) complexes U6AuCNPh and U6AuPPh3, respectively, as bioorganometallic conjugates. The crystal structure of U6AuCNPh revealed the formation of a head-to-tail dimer through the Au(I)–Au(I) and π–π interactions between the uracil and benzene...
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