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The porphyrins bearing two three-dimensionally regulated oligoaniline chains with terminal pyridyl groups were synthesized. The self-assembled branched polymer complex by introducing Zn(II) to the porphyrin was achieved in solution, which underwent dropcasting on the surface of mica to result in dome-like nanostructures.
Synthesis and Zn(II)-directed self-assembly of the porphyrin-aniline trimer bearing the pyridyl group were demonstrated. Its Au nanoparticle hybrid was also synthesized.
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