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Herein, we report a method to synthesize a series of alternating copolymers that consist exclusively of acrylamide units. Crucial to realizing this polymer synthesis is the design of a divinyl monomer that contains acrylate and acrylamide moieties connected by two activated ester bonds. This design, which is based on the reactivity ratio of the embedded vinyl groups, allows a “selective” cyclopolymerization,...
Doppelt hält besser: Sich periodisch wiederholende ABA‐Sequenzen in Copolymeren wurden mit einem monomeren Palladium‐Templat erhalten. Wichtig für die Polymerisation waren π‐π‐Wechselwirkungen zwischen aromatischen Seitengruppen, um drei Vinylgruppen gezielt anzuordnen (siehe Bild). Aufgrund dieser Wechselwirkungen war doppelte Cyclopolymerisation am monomeren Palladium‐Templat möglich. Entfernen...
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