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Meta‐C−H functionalization of benzylamines has been developed using a PdII/transient mediator strategy. Using 2‐pyridone ligands and 2‐carbomethoxynorbornene (NBE‐CO2Me) as the mediator, arylation, amination, and chlorination of benzylamines are realized. This protocol features a broad substrate scope and is compatible with heterocylic coupling partners. Moreover, the loading of the Pd can be lowered...
2,4,6‐Trimethoxypyridine is identified as an efficient ligand for promoting a Pd‐catalyzed ortho‐CH amination of both benzamides and triflyl‐protected benzylamines. This finding provides guidance for the development of ligands that can improve or enable PdII‐catalyzed CH activation reactions directed by weakly coordinating functional groups.
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