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Hydrogen-bonding interactions between α-hydroxyketones (i.e., (R)- and (S)-1-hydroxy-1-phenyl-2-propanones and (R)- and (S)-2-hydroxy-1-phenyl-1-propanones) and protonated cinchonidine in Open(3) conformation relevant to enantioselective hydrogenation over Pt were studied computationally at the B3LYP/TZVP level. The density functional theory (DFT)-optimized structures were reoptimized on a flat Pt(111)...
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