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Inverse‐electron‐demand Diels–Alder reaction (IEDDA) between fullerenes and 1,2,4,5‐tetrazine generally requires harsh conditions and long reaction times due to their strong electron‐accepting nature. Herein, we report a dramatic enhancement in the reactivity of the fullerenes (C60/C70)‐tetrazine reaction inside a porous Zn‐porphyrinic cage (Zn‐PB) under sustainable conditions by installing a tetrazine‐based...
Inverse‐electron‐demand Diels–Alder reaction (IEDDA) between fullerenes and 1,2,4,5‐tetrazine generally requires harsh conditions and long reaction times due to their strong electron‐accepting nature. Herein, we report a dramatic enhancement in the reactivity of the fullerenes (C60/C70)‐tetrazine reaction inside a porous Zn‐porphyrinic cage (Zn‐PB) under sustainable conditions by installing a tetrazine‐based...
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