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Aus drei wird eins: Die Titelverbindung (siehe Schema) kann in 26 Stufen durch eine doppelte Prins‐Cyclisierungsstrategie hergestellt werden. Die Route kombiniert zwei ähnliche Dioxinonfragmente und eine Aldehydkomponente für den Aufbau der Kernstruktur. (−)‐Exiguolid inhibiert bei niedriger Konzentration selektiv das Wachstum von A549‐Krebszellen; sowohl die Trien‐Seitenkette als auch die Z‐Enoat‐Geometrie...
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