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5-Carboxy-2′-deoxycytidine (dCCOO-) was synthesized as an anion-carrier to seek a new possibility of modified oligodeoxynucleotides capable of stabilization of duplexes and triplexes. The base pairing properties of this compound were evaluated by use of ab initio calculations. These calculations suggest that the Hoogsteen-type base pair of dCCOO--G is less stable than that of the canonical C +...
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