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The borylene–carbonyl moiety in [bis(silylene)B(CO)][WBr(CO)5] shows diverse reactivity. Reduction, migration, and complete cleavage of CO have been observed at the boron center, leading to the formation of new types of borylenes. These reactions not only serve as new methods for the synthesis of various stable borylenes, but also demonstrate that main‐group‐element compounds can mimic the behavior...
Monovalente Bor‐Verbindungen imitieren das chemische Verhalten von Übergangsmetallkomplexen. In ihrer Zuschrift auf S. 8844 beschreiben Z. Xie et al. diverse Reaktionen einer Borylen‐Carbonyl‐Verbindung mit verschiedenen Reduktionsmitteln und Nucleophilen, die z. B. zu CO‐Reduktion, ‐Migration und ‐Spaltung führen. Das Titelbild veranschaulicht die unterschiedlichen Reaktionen, die für diese Verbindung...
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