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A new tetradentate ligand 1,4-bis(5 -methyl-2,2 -bipyridine-5-ethyl)-benzene(p-bpy) and its Cu II and Ag I complexes were synthesized. In complex 1, Cu(p-bpy)[ClO 4 ] 2 0.5MeCN, the four nitrogen atoms of the ligand coordinate with one Cu II to form a flattened tetrahedron. The metal ion also has weak interactions with two ClO -4 ions,...
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