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A brief overview of theoretical and experimental aspects of the Dark state Exchange Saturation Transfer (DEST) and lifetime line broadening ( $$\Delta R_{2}^{{}}$$ Δ R 2 ) NMR methodologies is presented from a physico-chemical perspective. We describe how the field-dependence of $$\Delta R_{2}^{{}}$$ Δ R 2 can be used for determining the exchange regime on the transverse spin...
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