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α‐Mannosidases and α‐mannanases have attracted attention for the insight they provide into nucleophilic substitution at the hindered anomeric center of α‐mannosides, and the potential of mannosidase inhibitors as cellular probes and therapeutic agents. We report the conformational itinerary of the family GH76 α‐mannanases studied through structural analysis of the Michaelis complex and synthesis and...
Gut nachgemacht: Di‐ und Trisaccharidanaloga des Oxazolinintermediats der enzymatischen Hydrolyse von Chitin sind gute Chitinase‐A‐Inhibitoren. Wegen der hohen Affinität und enzymatischen Stabilität eines einfach zugänglichen Thioamidtrisaccharids (zwei Moleküle sind im aktiven Zentrum des Enzyms gezeigt) sowie der mechanismusbasierten Wirkungsweise ist dieses Analogon ein vielversprechender Kandidat...
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