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Homoleptic RuII complexes carrying rigid linkers for attachment to semiconductor surfaces were synthesized by using the click reaction. Star‐shaped complexes KStar‐TzC‐pBn (1a) and KStar‐TzC‐Ipa (1b), composed of 2,2′‐bipyridine ligands 4,4′‐disubstituted with 1,2,3‐triazole rings connected to the Ru complex through the C4 of the 1,2,3‐triazole (Tz) ring and capped with p‐benzoic (pBn) and isophthalic...
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