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NO reduction by CO was investigated over a AuPd(100) model catalyst at near atmospheric pressures. The alloy catalyst exhibits higher CO 2 formation rates below ∼550K than does pure Pd, although the binding energy of NO on the alloy surface is substantially less, i.e., its dissociation tendency is much less, compared with pure Pd. This behavior is rationalized by the fact that the low CO/NO-binding...
RuO 2 (110) was formed on Ru(0001) under oxygen-rich reaction conditions at 550K and high pressures. This phase was also synthesized using pure O 2 and high reaction temperatures. Subsequently the RuO 2 was subjected to CO oxidation reaction at stoichiometric and net reducing conditions at near-atmospheric pressures. Both in situ polarization modulation infrared reflection...
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