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SummaryA new fluorescent initiator fluorescein 2-bromoisobutyrate (Flu-Br) was synthesized. The use of Flu-Br as initiator, Me6TREN as ligand and CuCl as catalyst by atom transfer radical polymerization allowed for chain-end fluoresceined poly(N-isopropylacrylamide) (Flu-PNIPAM) in one step. The polymerization reached high conversion (65%) and low polydispersity (PDI) (1.15∼1.28). The linearity plot...
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