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The syntheses, crystal structures, magnetic and luminescent properties of three isomorphous compounds [LnIII6(µ4-O)2(C4A)2-(NO3)2(HCOO)2(CH3O)2(DMF)4(CH3OH)4] (Ln = Gd (1), Tb (2) and Dy (3); H4C4A = p-tert-butylcalix[4]arene) are reported. These three compounds are featured with the sandwich-like units constructed by two tail-to-tail calixarene molecules and an in-between LnIII6 octahedron. The...
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