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The substances SrM3P4O14 (M = Mn, Fe, Co or Ni) have the same crystal structure. However, the magnetism of SrMn3P4O14 differs qualitatively from that of the other substances. We determined the magnetic structures of SrM3P4O14 (M = Mn or Co) by using neutron powder diffraction measurements. The spin system in SrMn3P4O14 can be regarded as a trimerized spin chain, which is consistent with the spin...
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