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Detailed kinetic studies on the ligand‐substitution reactions of the very labile [Pd(terpy)Cl]+ (terpy = 2,2′:6′,2″‐terpyridine) complex have been performed for neutral and anionic nucleophiles in several imidazolium‐based ionic liquids. The detailed substitution mechanisms derived from the obtained rate and activation parameters differ from those expected on the basis of data aquired in aqueous medium,...
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