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The mononuclear oxidovanadium(V) complex [VO(L)(OEt)(EtOH)] (1), where H 2 L=Salicyloyl hydrazone of diacetyl monooxime, reacts separately with five different reactants viz. pyridine (py), 4-methylpyridine (4mepy), 4,4′bipyridine (4,4′bipy), 8-hydroxyquinoline (Hox) and KOH to yield the mononuclear oxidovanadium complexes [VO(L)(OEt)(py)] (2), and [VO(L)(OEt)(4mepy)] (3), the binuclear complex...
The reaction of VO(acac) 2 with the ONO-chelator obtained by the condensation of salicylaldehyde with 2-hydroxybenzoylhydrazine (H 2 L) in a monohydric alcohol (ROH) medium produces [VO(OR)L]-type oxidoalkoxido complexes (1–7) where R=Me, n Pr, i Pr, n Bu, i Bu, t Bu and n Pen. All the complexes show the metal atom to have a five-coordinate...
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