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The trans-PtH2(P(OMe)3)2 complex was synthesized and tested as a nitrile hydration catalyst. Under nitrile hydration reaction conditions, the complex degrades to Pt nanoparticles, which are catalytically active for nitrile hydration. TEM analysis shows that the Pt nanoparticles are approximately 2 nm in diameter. 31P NMR and XPS studies of the nanoparticles show that the stabilizing ligand on the...
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