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Carbodicarbene (CDC) has become an emerging ligand in many fields due to its strong σ‐donating ability. <We report the first synthesis of the anionic CDC Pd complexes containing a BF2‐ moiety within the framework to leverage the electronic feature of carbon carbone. The elucidation of X‐ray crystal structures, ligand competition as well as transmetallation experiments suggest that the anionic moiety...