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Porous Salts
In article number 2207507, Eric D. Bloch and co‐workers present a novel approach toward constructing reactive, porous solids. The porous salt, built upon an anionic cage balanced by a cationic chromium(II) complex, is successfully characterized using a plethora of spectroscopic techniques and single crystal X‐ray diffraction (XRD). The site‐isolated chromium(II) centers readily activate...
The preparation of a new class of reactive porous solids, prepared via straightforward salt metathesis reactions, is described here. Reaction of the dimethylammonium salt of a magnesium‐based porous coordination cage with the chloride salt of [CrIICl(Me4cyclam)]+ affords a porous solid with concomitant removal of dimethylammonium chloride. The salt consists of the ions combined in the expected ratio...
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