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Aminosilylene, comprising reactive NH− and Si(II) sites next to each other, is an intriguing class of compounds due to its ability to show diverse reactivity. However, stabilizing the reactive NH− group next to the free Si(II) atom is challenging and has not yet been achieved. Herein, we report the first examples of base stabilized free aminosilylenes Ar*NHSi(PhC(NtBu)2) (1 a) and Mes*NHSi(PhC(NtBu)...
Herein, we report the stabilization of nitrene reagents as the source of a nitrogen atom to synthesize nitrogen‐incorporated R1LSi‐N←SiLR2 (1) [L=PhC(NtBu)2; R1=NTMS2, R2=NTMS]. Compound 1 is synthesized by reacting LSi(I)‐SiIL with 3.1 equivalents of Me3SiN3 at low temperature to afford a triene‐like structural framework. Whereas the reaction of the LSi(I)‐SiIL with 2.1 equivalents of Me3SiN3 at...