The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
Epoxidation of olefins by tert-butyl hydroperoxide (TBHP) was effectively catalyzed by a cubic silicon-titanium μ-oxo-complex, which is obtained from a bulky silanetriol and titanium alkoxides. The stoichiometric reaction of the complex with TBHP in the absence of olefin formed a novel complex as white solid. The comparison of this product with analogous complexes in 1 H and 13 ...
Flash vacuum pyrolysis (FVP) of the N-(adamantan-1-yl)hexafluorothioacetone S-imide (1b) yielded an isomeric compound 4 without extrusion of the sulfur atom. On the other hand, thermolysis of the same S-imide in CDCl3-solution afforded dithiazolidine 5 as the main product. Thermal cleavage of 1b leading to in situ formation of hexafluorothioacetone is the primary reaction in solution. [3+2]-Cycloadditions...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.