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Preparation of porous materials from one‐dimensional polymers is challenging because the packing of polymer chains results in a dense, non‐porous arrangement. Herein, we demonstrate the remarkable adaptation of an amorphous, linear, non‐porous, flexible organic polymer into a three‐dimensional, highly porous, crystalline solid, as the organic component of a metal–organic framework (MOF). A polymer...
Hybridmaterialien In der Zuschrift auf S. 6250 ff. beschreiben S. M. Cohen et al. die Umwandlung von nichtporösen, eindimensionalen, amorphen Polymeren in kristalline polymerbasierte Metall‐organische Gerüstmaterialien.
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