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Doppelt hält besser: Triphenylphosphinazin, N2(PPh3)2, ist ein Donor‐Akzeptor‐Komplex von im hochangeregten 1Γg‐Zustand befindlichen Distickstoff und zwei antiperiplanar koordinierten Phosphinliganden (siehe Struktur). Obwohl die Dissoziation in N2 + 2 PPh3 mit ca. 75 kcal mol−1 als exergonisch berechnet wird, ist die Verbindung wegen der starken Lewis‐Acidität von N2 im angeregten 1Γg‐Zustand kinetisch...
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