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New two-dimensional metal–organic frameworks [Pb(Hbidc)] n (1) and [Cd(Hbidc)] n (2), constructed from multidentate ligand 1H-benzimidazole-5,6-dicarboxylic acid (Hbidc), have been synthesized under hydro/solvothermal conditions and fully characterized. Compound 1 is the first lead–organic framework based on Hbidc, and displays a 5-connected SnS network which contains 2D [Pb(CO ...
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