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A tris(2-aminoethyl)amino triamide derivative anion receptor has been tested as electroactive material for the development of anion-selective electrodes. The receptor was incorporated in plasticized poly(vinyl chloride) membranes of different compositions. The membrane that provided the best response and selectivity towards nitrate was selected to develop a new nitrate-selective electrode. The electrode...
Two different modes of stabilisation of the α-carbocationic centre in the diferrocenylcarbenium ion 4, available from the [5]ferrocenophane 1 by sequential treatment with ferrocenyllithium and tetrafluoroboric acid, are clearly demonstrated by a combination of 1 H NMR and 57 Fe Mössbauer spectroscopies.
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