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Autocorrelation analysis of infrared spectra can provide insights on the strain energy associated with cation substitutions along a solid-solution compositional join which to date has been applied primarily to silicate minerals. In this study, the method is applied to carbonates synthesized at 10 mol% increments along the calcite–dolomite (CaCO3–CaMg(CO3)2) join in the range of 1000–1150 °C and 0...
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