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A metal‐containing N‐heterocyclic germylene based on a N‐mesityl (Mes)‐substituted oxalamidine framework is reported. The precursor (MesN=)2C–C(–N(H)Mes)2 (1H2) was converted into its rhodium complex [Rh(κ2N‐1H2)(cod)][OTf] (2) (cod = 1,5‐cyclooctadiene; OTf = triflate) in 62 % isolated yield. Subsequent reaction of 2 with Ge{N(SiMe3)2}2 gave the crystalline N‐heterocyclic germylene [Rh(cod)(μ‐1)Ge][OTf]...
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