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A series of three Mo2 dimers bridged by a meta‐phenylene group has been studied in terms of electronic coupling (EC) and electron transfer (ET) in comparison with the para isomers. Optical analyses on the mixed‐valence complexes indicate that by replacing a para‐phenylene bridge with a meta one, the EC between the two Mo2 centers is dramatically weakened; consequently, the ET rates (ket) are lowered...
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