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Copolymerization of ethylene with 1‐octadecene was studied using [η5:η1‐C5Me4‐4‐R1‐6‐R‐C6H2O]TiCl2 [R1 = tBu (1), H (2, 3, 4); R = tBu (1, 2), Me (3), Ph (4)] as catalysts in the presence of Al(i‐Bu)3 and [Ph3C][B(C6F5)4]. The effect of the concentration of comonomer in the feed and Al/Ti molar ratio on the catalytic activity and molecular weight of the resultant copolymer were investigated. The substituents...
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