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Cyanide-bridged Mn II M III coordination polymers, [Mn(dien)] 3 [M(CN) 6 ] 2 ·2H 2 O (M=Cr (1), Mn (2); dien=diethylenetriamine), have been prepared by using [M(CN) 6 ] 3− building units and a tridentate dien as a coligand. Single crystal and powder X-ray diffraction results of 1 and 2 proposed that the compounds are isomorphous and form...
A 2-D cyanide- and triamine-bridged Mn II Cr III ferrimagnet, [Mn 3 (dien) 2 (H 2 O) 2 ][Cr(CN) 6 ] 2 ·4H 2 O (1), has been prepared by the combination of Mn 2+ , diethylenetriamine (dien) co-ligand and [Cr(CN) 6 ] 3− . This compound forms a unique 2-D hollow sheet structure constructed by 1-D ribbon networks...
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