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Silver(I) complexes of pyiridine‐containing macrocyclic ligands (Pc‐L) have already been demonstrated as active catalysts for some domino and multicomponent reactions. Here, we report new chiral [AgI(Pc‐L*)] cationic complexes that have been synthesized and fully characterized, including structural determination by single‐crystal X‐ray diffraction. The complexes show a rich coordination chemistry,...
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