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This paper reports the sintering behavior of synthetic inorganic carbonates chemically identical to barytocalcite (BaCa(CO3)2, 8.1wt.% C), kutnahorite (CaMn(CO3)2, 11.1mass% C) and rhodochrosite (MnCO3, 10.5wt.% C) for 14C immobilization. As carbonates are time–temperature dependently subjected to decarbonation due to the loss of carbon dioxide, spark plasma sintering (SPS) appeared to be the most...
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