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DFT methods have been applied for the calculation of several ground-state properties of neutral and charged ruthenium(II) and osmium(II) tin trihydride complexes bearing N-donor, P-donor and C-donor ancillary ligands in their coordination sphere. Complexes of the type M(SnH 3 )(Tp)(PPh 3 )P(OMe) 3 , M(SnH 3 )(Cp)(PPh 3 )P(OMe) 3 and [M(SnH 3 ...
Iron and ruthenium classical and non-classical hydrides of the type [MH(N–N)P 3 ] + and [M(η 2 -H 2 )(N–N)P 3 ] 2+ {M=Fe, Ru; N–N=2,2′-bipyridine (bpy), 1,10-phenanthroline (phen); P=phosphites} were reported in 2004 together with an evaluation of the pseudo-aqueous pK a values of the η 2 -H 2 complexes. The non-classical hydrides,...
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