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Three aluminium salophen and two aluminium salen complexes were synthesised, characterised and screened in the ring-opening polymerisation (ROP) of rac-lactide and rac-β-butyrolactone. The focus was on controlling the apparent polymerisation rate (k p ) and stereoselectivity of poly(lactic acid) and poly(3-hydroxybutyrate) by modulating the electron density at the aluminium centre or by switching...
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