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This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by heterofunctionalized phosphines and by hard and soft scorpionates. The main goal is to provide the reader with chemical, radiochemical and biological knowledge which is expected to enhance the application of these types of compounds in the development...
In recent years, the remarkable characteristics of the organometallic precursor fac-[M(CO) 3 (H 2 O) 3 ] + (M = Re, Tc) introduced by Alberto and co-workers brought renewed interest to the development of low-oxidation 99m Tc-based radioactive probes. Considering our interest in the design of target-specific radioactive probes for SPECT-imaging and targeted systemic...
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