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Irradiation of cationic complexes belonging to the [CpFe(η 6 -arene)] + family (Cp is η 5 -C 5 H 5 ) results in the substitution of arene by solvent or other potential ligands present in solution. In solutions containing an epoxide monomer, this photochemical reaction generates a species that initiates polymerization. While several studies of this commercially...
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