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Prospects in light‐driven water activation have prompted rapid progress in hydrogenation reactions. We describe a Ni2+−N4 site built on carbon nitride for catalyzed semihydrogenation of alkynes, with water supplying protons, powered by visible‐light irradiation. Importantly, the photocatalytic approach developed here enabled access to diverse deuterated alkenes in D2O with excellent deuterium incorporation...
Prospects in light‐driven water activation have prompted rapid progress in hydrogenation reactions. We describe a Ni2+−N4 site built on carbon nitride for catalyzed semihydrogenation of alkynes, with water supplying protons, powered by visible‐light irradiation. Importantly, the photocatalytic approach developed here enabled access to diverse deuterated alkenes in D2O with excellent deuterium incorporation...
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